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The rising star and then-boyfriend Brad Pitt sported matching blonde locks at The Devil's Own premiere in NYC in 1997.

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In 1999, she nabbed an Oscar for Best Leading Actress wearing Ralph Lauren's taffeta dress for her breakthrough role in Shakespeare In Love.

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he following year, she attended the awards show in a club-wear meets yoga ensemble.

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The star buttoned up pal Stella McCartney's chic tailored blazer with a glitzy bohemian skirt at the 2001 VH1/Vogue Fashion Awards in 2001. Her other fave fashion designers? Alexander McQueen, Carolina Herrera, and Junya Watanabe.

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Critics slammed Paltrow for her fashion and beauty faux pas at the Academy Awards in 2002: a see-through dress paired with severe-looking cornrows.

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The pregnant star showed off her newfound curves in a two-toned biased cut Stella McCartney dress in 2004.

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Paltrow looked lovely in nude colored strapless dress at the Vanity Fair Oscar Party in 2005.

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The actress picked a Zac Posen dress and straightened her long locks at the 2007 Academy Awards.

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The star debuted a shorter 'do and rocked a slim blazer over Alexander McQueen's strapless dress at an event in London March 18.

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She took her hemline to new heights at the Iron Man premiere in London April 24